Materials Science Forum Vols. 302-303 (1999) pp. 64-75 Magnetic Multilayers: Interlayer Coupling in Fe/Cr/Fe S.M. Rezende, C. Chesman, M. A. Lucena, M. C. de Moura, A. Azevedo and F. M. de Aguiar The exchange coupling between neighbouring magnetic layers in multilayer system consisting of stacks of ferromagnetic layers separated by nonmagnetic metallic layers plays central role in the properties of these novel artifically structured materials. Here we review the most common techniques for measuring this couling, namely magneto-optical Kerr effect magnetometry, Brillouin light scattering and ferromagnetic resonance. The theoretical background for interpreting experimental data in trilayers formed by two magnetic layers separated by a nonmagnetc layer is presented, based on phenomenological model energy including bilinear and biquadratic exchange couplings, as well as surface, in-plane uniaxail and crystalline cubic anisotropy contributions. Accurate quantitative values for the coupling constants and the other magnetic parameters are measured in the prototype system (100) Fe/Cr/Fe grown by sputtering for several Cr spacer thickness. Consistent values are obtianed with all three techniquesd for both the bilinear (J1) and biquadratic (J2) exchange coupling constant. In most of the Cr thickness range corresponding to the first antiferromagnetic peak, J2 follows J1 with a ration J2/|J1|~0.1. In the range corresponding to the second antiferromagnetic peak J2 also follows J1, but with a much larger ratio J2/|J1|~1.0 indicating that the origin of the biquadratic coupling in the two ranges resides in different mechanisms.