Hyperfine Interactions 126 (2000) 353-361 Synchrotron Mössbauer reflectometry D.L. Nagy, L. Bottyán, L. Deák, E. Szilágyi, H.Spiering, J.Dekoster and G. Langouche D.L. Nagy, L. Bottyan, L. Deak, E. Szilágyi, H.Spiering, J.Dekoster and G. Langouche KFKI Research Institute for Particle and Nuclear Physics, P.O. Box 49, H-1525 Budapest, Hungary Institut für Anorganische und Analytische Chemie, Johannes Gutenberg Universitat Mainz, Staudinger Weg 9, D-55099 Mainz, Germany Instituut voor Kern- en Stralingsfysica, K.U. Leuven, Celestijnenlaan 200 D, B-3001 Leuven, Belgium Grazing incidence nuclear resonant scattering of synchrotron radiation can be applied to perform depth-selective phase analysis and to determine the isotopic and magnetic structure of thin films and multilayers. Principles and recent experiments of this new kind of re-flectometry are briefly reviewed. Methodological aspects are discussed. Model calculations demonstrate how the orientations of the sublattice magnetisation in ferro- and antiferromag-netic multilayers affect time-integral and time-differen tial spectra. Experimental examples show the efficiency of the method in investigating finite-stacking, in-plane and out-of-plane anisotropy and spin-flop effects in magnetic multilayers.